The carbon steel casings of heat recovery steam generators hrsgs in a cogeneration plant were found to have developed cracks that originated on the inside surfaces. Pdf stress corrosion cracking of carbon steel in nitrate. Stress corrosion cracking scc in boilers and cooling. Predicted growth of throughthickness stress corrosion. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack. Stress corrosion cracking of astm a517 steel in liquid. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the cracking mechanism on brass which occurs in an aqueous solution. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stresscorrosion cracking scc in aircontaminated dry ammonia. A stainless steel seems like a better choice for this application. Four types of metal products uncoated 1010 carbon steel, galvanized steel, galvalume, and pure zinc were evaluated for weight losses and corrosion rates over a twomonth test period. Evaluation of ammonia hydroxide for mitigating stress. Amines are compounds formed by replacing hydrogen atoms of ammonia, nh3 by organic radicals. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Stresscorrosion cracking, materials performance and. Brass condenser tubes can undergo brittle fracture if bent when significant ammonia stress corrosion cracking is present. Ammonia at normal atmospheric temperatures and pressures is a gas. Ammonium chloride these corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen. Borode school of chemical and metallurgical engineering, faculty of engineering and the built. Stresscorrosion cracking of steels in ammonia with. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking scc in boilers and cooling water. Stress corrosion cracking of brass in ammonia uk essays.
Aug 03, 2011 copper alloys can be attacked by carbon dioxide depending on what oxidants, including dissolved oxygen, are present. A typical indication for this kind of damage is the branched cracks of fig. Stress corrosion cracking of steel occurs in the coc02h20 system when these three environmental components are present together. Stress corrosion cracking international institute of. A study was made to determine relevant growth data and to determine methods to prevent cracking. The harmful effect of grinding upon the resistance of steel to stresscorrosion cracking, very much in evidence in specimens with a martensitic structure, is negligible in the case of steel with a sorbitic structure. Stress corrosion cracking scc in low and medium strength. Also the return of empty transport tanks can be a source of oxygen. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Astm b858 062018 standard test method for ammonia vapor. Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Material damage due to hydrogen embrittlement and stress corrosion cracking can be classed as cases. Crack development in carbon steel exposed to nitrate solution.
Carbon steel corrosion in aqueous ammonia high temperature system. A laboratory study on metal corrosion by ammonia gas. Stress corrosion cracking in brass is usually localised and, if ammonia has been involved, may be accompanied by black staining of the surrounding surface. Stress corrosion cracking of brass in nonammoniacal solutions 15 stress corrosion cracking of pure copper 21 summary of stress corrosion cracking studies. By detailed metallurgical tests it was proven that the failure had been brought about by stress corrosion cracking. Similar but accelerated laboratory test was subsequently conducted in such a way as to mimic the field failures.
Stress corrosion cracking of cuzn and cua1 alloys in cuprous ammonia. Prevention of stress corrosion cracking of carbon steels in. Ammonia corrosion can cause stress corrosion cracking in steels. It has been found that scc in fge can be inhibited by adding inhibitors. Department of transportation regulations provide effective safeguards to prevent this problem through the required use of postweld heat treatment and the use of 0. There are no known fatalities due to stress corrosion cracking in ammonia refrigeration vessels, and no reported cases of vessels rupturing or fracturing in service. Many stress corrosion crack accidents of ammonia storage tanks have been reported all over the world for recent years. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment.
The growth of stress corrosion cracks increased with stress intensity factor and decreased with exposure time. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. Anhydrous ammonia is one of the medium where the steel is easy to suffer stress corrosion cracking. Within the iso committee tc 26sc 2, wrought copper and copper alloys, a working group, wg4, has been set up to propose an ammonia test to evaluate the stress corrosion resistance of copper alloy products. Carbon steel is susceptible to stress corrosion cracking scc in fuel grade ethanol fge. The hrsgs receive hot exhaust gases from the primary gas turbines gts, which are fuelled with pipeline natural gas. Carbonate stress corrosion of the mains springerlink. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
Stresscorrosion cracking of steel occurs in the coc02h20 system when these three environmental components are present together. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks. The process does not proceeds indefinitely since the attack of cupric complex ion oxide layer occurs at critical copper ion content which leads to decrease in corrosion rate but the cracking continues with the copper ion concentration. Nitrate stress corrosion cracking of carbon steel equipment authors frank n. Nitrate stress corrosion cracking of carbon steel equipment.
Ammonia test for stress corrosion resistance of copper alloys. Stainless steels are more resistant to general corrosion compared with carbon steel. Stress corrosion cracking scc in carbon steel transport. The dissolved carbon monoxide in the water forms an inhibitive layer on the surface of the steel. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Typically the indication of a leak due to stress corrosion cracking is a strong smell of ammonia gas seeping through a short hairline crack on a pressure vessel. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Scc is the phenomena of cracks being formed in carbon steel in. Jun 09, 2014 avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. Stress corrosion cracking of carbon steel storage tanks for. It can be stored under pressure as a liquid or below its atmospheric boiling point of 34 degc. Stress corrosion cracking of carbon steel springerlink. Overview of stress corrosion cracking scc in water systems.
Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. The effects of aerial ammonia on metal corrosion was examined in this study. Sep 23, 2008 corrosion effect of carbon dioxide and ammonia on carbon steel tower 2005. Stress corrosion cracking is caused by the combination of stress in the tanks steel and the corrosive effect of ammonia. Refer to other fact sheets for specific discussion of issues related to corrosion in general, external corrosion, internal corrosion, and selective seam corrosion. Copper alloys can be attacked by carbon dioxide depending on what oxidants, including dissolved oxygen, are present. Increasing the plasticity of the steel causes a reduction in its proneness to stresscorrosion cracking, which does not occur at all in specimens tempered at 550c.
Measures for reducing scc in anhydrous ammonia storage tanks. Another form of ammonia scc afflicts carbon steel equipment. The stresscorrosion cracking of carbon steel in coc02h20. Corrosion effect of carbon dioxide and ammonia on carbon steel tower 2005. Stress corrosion cracking of steel in liquefied ammonia service a. The scc of carbon and alloy steels in ammonia service has occurred. There is some good information available from european fertiliser manufacturers association efma about this.
Stress corrosion cracking scc is produced by the simultaneous interaction of three essential factors. During stress corrosion cracking, the metal or alloy is virtually unattacked. Stress corrosion cracking of carbon steel storage tanks. Through an investigation of the field failure analysis and laboratory experiment, a study on stress corrosion cracking scc behavior of steel and aluminum was performed. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Scc in pipelines is a type of environmentally assisted cracking.
Selection of stainless steels for handling ammonia nh3. Selection of stainless steels for handling ammonia nh3 introduction. Electrochemistry of stress corrosion cracking of brass by m. Ammonia stress corrosion cracking a mmonia stress corrosion cracking scc is the phenomena of cracks being formed in carbon steel in contact with ammonia. This paper reports the work conducted to evaluate nh4oh as an inhibitor to mitigate scc of carbon steel in simulated fge sfge. Stress corrosion cracking of steel and aluminum in sodium. Damage due to hydrogen embrittlement and stress corrosion. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. The formation of cupric complex ions leads to stress corrosion cracking of brass in ammonia solutions. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Stress corrosion cracking scc corrosion and failure. All samples were extracted from known operating conditions from the field failures. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades.
Electrochemistry of stress corrosion cracking of brass. Specialized corrosion doehdbk1015193 corrosion ch02 rev. Apart from the classically known hydroxide and nitrate media, stress corrosion cracking of such steels has been reported in a number of other environments, namely aqueous chloride, carbonate, phosphate, ammonia, coco 2h 2 o, high purity water containing oxygen, fuel ethanol and several. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Stress corrosion cracking sco of carbon and alloy steels in liquid ammonia has occurred spasmodically over the last twenty years. Astm b858062018, standard test method for ammonia vapor test for determining susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2018, back to top. Hennecken 16 states that high oxygen contents in the ammonia require increased water contents to provide inhibition against scc in carbon steel, and. Elements such as molybdenum, manganese and chromium had a positive effect on the resistance to nitrate induced iga, saiga and stress corrosion cracking, whereas carbon and copper were detrimental. Copper alloys see other formats r a d a 0 1 2 872 stress corrosion cracking 3. Prevention of stress corrosion cracking of carbon steels.
The cracks are small at the surface but can be deep, worstcase going through the entire thickness of the metal. Corrosionpedia what is stress corrosion cracking scc. Avoiding stress corrosion cracking of carbon low alloy and. Scc stress corrosion cracking leaflet product stewardship. The reduction of crack growth rate with time is mainly caused by a crevice corrosion attack in the outer part of the crack. Polythionic acid is another environment, which causes scc in austenitic stainless steels. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Copper alloys can also suffer stress corrosion cracking and other forms of attack in ammonia service. Stress corrosion crack growth of carbon steel in ammonia was studied with compact tension specimens. Stress corrosion cracking of steel in liquefied ammonia. It is shown that carbonates and bicarbonates are responsible for the major part of events of corrosion cracking in the mains with cathodic protection caused by local damages to protective coatings and, possibly, for the events of fracture without cathodic protection. Stress corrosion crack tests of 16mnr low alloy steel in.
Carbon steels in anhydrous ammonia service can suffer from stress corrosion cracking if the water content is less than about 0. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Mercury stress corrosion cracking of brass components can also occur in service due to contamination from broken thermometers. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
The growth of stress corrosion cracks increased with. The unsolved problems 23 experimental 27 material 27 stress corrosion cracking samples 27 electrochemical tests samples 27 solutions 28 measurement techniques 29. The stress corrosion cracking scc of carbon steel in nitratecontaining environments has been known for a long time and has become important in managing the integrity of aging underground. Within the iso committee tc 26sc 2, wrought copper and copper alloys, a working group, wg4, has been set up to propose an ammonia test to evaluate the. Stresscorrosion cracking in aluminum alloys is characteristically intergranular. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the cracking mechanism on brass which occurs in an aqueous solution, the cracking of steel equipment occurs in anhydrous ammonia.
What is stress corrosion cracking and why does it occur. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stress corrosion cracking scc in aircontaminated dry ammonia. Problems with amine units can be corrosion or by cracking sulphide stress cracking, hydrogen induced. Neutron diffraction analysis was used to map the residual stress state in and near circumferential welds from two used anhydrous ammonia nurse tanks, one manufactured in 1966 and the other manufactured in 1986. Carbon steel corrosion in aqueous ammonia high temperature. Mild steels steels with low carbon and low alloy content and stainless steels will.
The harmful effect of grinding upon the resistance of steel to stresscorrosion cracking, very much in evidence in specimens with a martensitic structure, is negligible in the. Chemicals other than water, like ammonia, can induce subcritical crack propagation in silica. Stresscorrosion cracking of steel in liquefied ammonia is traced from its early recognition in the 1950s, from experiences in agricultural and industrial use from nace national association of corrosion engineers recommended dot department of transportation regulations to prevent damage, and from laboratory studies to explain the factors involved. The specificity of environments that will promote stress corrosion cracking is significant. Unlike the cracking mechanism on brass, which occurs in an aqueous solution, the cracking of steel equipment occurs in anhydrous ammonia just the opposite. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Moustafa said seleet a dissertation submitted to the graduate faculty in partial fulfillment of the.